Courses: The GoldSim Contaminant Transport Module:

# Unit 9 - Modeling Spatially Continuous Processes: Advectively Dominated Transport with Dispersion

# Lesson 6 – Exercise: Using an Aquifer Element to Model a Groundwater Pathway

Now that we know how to use an Aquifer element and also understand the basics of how it works, in this Lesson we will work through a simple Exercise.

This example is shown schematically below:

A square trench is dug into the ground (with a very shallow water table) and some waste is deposited into a sandy aquifer so that it is entirely below the water table (this obviously would be a very bad way to dispose waste!). The waste contains two contaminants (X and Y) that are present at a fixed concentration effectively indefinitely (e.g., due to a solubility constraint). This forms a contaminant plume that flows along the water table. Species X is sorbed onto the sand, but species Y is not sorbed at all. The entire plume eventually discharges to a stream and is quickly mixed across the width and depth of the stream. For the purpose of this simple Exercise, we will assume that the flow rate through the aquifer and in the stream is constant. Our objective is to predict the concentration of the contaminants downgradient of where the groundwater plume discharges into the stream (at a distance where the stream is assumed to be well-mixed).

The various input parameters describing this system are summarized below:

Variable | Value |
---|---|

Fixed concentration at source | 100 mg/l for both X and Y |

Dispersivity Fraction (fraction of length) | 10% |

Sand Saturated Hydraulic Conductivity | 5E-4 m/s |

Sand Bulk Density | 1600 kg/m3 |

Sand Porosity | 0.3 |

Sand Partition Coefficient | X = 0.0002 m3/kg; Y = 0 m3/kg |

Distance to Stream | 1 km |

Hydraulic Gradient in Aquifer | 1% |

Trench Depth (top of water table to bottom of trench) | 10 m |

Trench Width | 5 m |

Stream Flow Rate | 300,000 m3/day |

Stream Reach Volume downstream of plume | 75 m3 |

To create this model, you should start with a new model and follow these steps:

- Edit the Species element and make sure there are two species (X and Y).
- Create Data elements for the inputs in the table. Note that the partition coefficients and the source concentration should be defined as a vector of species.
- Add a Solid called Sand and define the partition coefficients, density and porosity.
- Create a Cell representing the Trench. Specify it as having a Defined Concentration (equal to the source concentration provided in the table). The volume of this Cell is unimportant since we are assigning a fixed concentration (so you can give it an arbitrarily small volume).
- Create a Cell representing the stream and assign it the reach volume in the table. This simply represents the volume of water in the reach downstream of where the groundwater plume discharges (and the mass becomes well-mixed).
- Create a Cell representing the Sink (assign it a volume of 1 m3).
- Create an Aquifer element and define all of its properties as specified in the table. The
**Length**is simply the distance to the stream. Define the**Area**as the trench depth multiplied by the trench width (we will discuss this assumption below). The**Dispersivity**should be the distance to the stream multiplied by the dispersivity fraction. You can leave it at the default value of using 10 Cells. - Create an advective mass flux link from the trench to the Aquifer element. The flow rate can be computed as the pathway
**Area**multiplied by the hydraulic conductivity multiplied by the gradient. - Create an advective mass flux link from the Aquifer element to the stream. You can use the same flow rate that entered the Aquifer. We will discuss the implications of this assumption further below.
- Create an advective mass flux link from the stream to the sink (using the stream flow rate).
- Finally, in the Time Settings, set the
**Duration**to 10 years, and the timestep to 0.1 yrs. Set the**Time Display Units**to yr.

Stop now and try to build and run the model.

** Once you are done with your model, save it to the “MyModels” subfolder of the “Contaminant Transport Course” folder on your desktop (call it ExerciseCT12.gsm)**. If, and only if, you get stuck, open and look at the worked out Exercise (ExerciseCT12_Aquifer.gsm in the “Exercises” subfolder) to help you finish the model.

Let’s walk through the model now.

If you organized all of your inputs in one Container and the pathways in another, the pathways Container should look similar to this:

Let’s look at the Aquifer element (named Saturated_Zone here):

In Lesson 4, we noted that the **Area **is the cross-sectional area of at the ** downstream end of the pathway **(perpendicular to the flow). In this case, however, we defined the

**Area**as the cross-sectional area at the

**(the trench depth multiplied by the trench width). That is, we are assuming that the vertical and transverse spread of the plume along the flow path is negligible (i.e., the**

*beginning of the pathway***Area**of the pathway remains constant along its length). In most natural systems, of course, this is not accurate, as due to the spreading of the plume, it will entrain some clean water (and the

**Area**will increase unless it is somehow constrained by neighboring impermeable materials). In fact, as we will see in Lesson 13, due to horizontal (transverse) and vertical dispersion, the actual area of the plume would likely be considerably larger than the source area by the time it discharges into the stream. We could have assumed a larger

**Area**to account for this. Doing so, however, would not impact the result we are trying the compute (the concentration in the stream). If we increased the

**Area**here, we would also need to increase the flow rate leaving the pathway accordingly. As a result, the flow rate entering the pathway would be less than the flow rate leaving the pathway, and this would indeed result in a decrease of the average concentration leaving the pathway due to this dilution. But this output (the average concentration leaving the pathway) is not very meaningful in this model (and as discussed in Lesson 4, is rarely meaningful); it is not something we are interested in. We are interested in the concentration in the stream. And changing the

**Area**(and the corresponding flow rate) does not have any impact on the travel time of the contaminants or the mass transfer rate into the stream (and hence the concentration in the stream). Of course, it is critical here that the flow rate we specify leaving the pathway be consistent with the

**Area**that we specify (the flow rate increases linearly with the

**Area**).

Note that the plume flow rate (which in this case represents the flow both leaving and entering the pathway) is computed as follows:

Let’s now open the Stream Cell. What does the volume represent? Physically, we can think of it as being on the order of the river length over which we can assume complete mixing (we’ll assume 3 widths of the plume) multiplied by the width of the stream multiplied by the depth of the stream. Recalling that the plume width is 5 m, and assuming a stream width of 5 m and a stream depth of 1 m produces a value of 75 m3. Such a small volume “turns over” very rapidly: 75 m3 divided by 300,000 m3/day results in a that volume being flushed in less than a minute. As such, it responds effectively immediately to any changes in the mass rate from the plume. If we assumed a considerably larger plume area (and hence a larger volume for the Stream Cell, it would still flush very rapidly, hence our results are not sensitive to this volume.

If we run this model and plot the concentration in the stream it should look like this:

Because X partitions onto the sand in the groundwater pathway, its breakthrough curve is delayed. Ultimately, however, steady state is achieved and both species reach the same concentration in the stream. In this very simple model this steady-state concentration is simply equal to the rate at which mass is entering the system (the plume flow rate multiplied by the concentration) divided by the stream flow rate.

*Make sure that you save this model to the “MyModels” subfolder of the “Contaminant Transport Course” folder on your desktop (call it ExerciseCT12.gsm), as we will revisit it later in this Unit.*